WINTERTIME VARIATION OF PEROXYACETYL NITRATE IN SAPPORO JAPAN
نویسندگان
چکیده
منابع مشابه
Transport pathways of peroxyacetyl nitrate
Introduction Conclusions References Tables Figures
متن کاملPeroxyacetyl nitrate (PAN) and peroxypropionyl nitrate (PPN)
Atmospheric Chemistry and Physics Discussions This discussion paper is/has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP if available. Abstract Peroxyacetyl nitrate (PAN) and peroxypropionyl nitrate (PPN) were measured sequentially in situ by an online gas-phase chromatograph with electron capture detector at urba...
متن کاملReaction of peroxyacetyl nitrate with glutathione.
Peroxyacetyl nitrate reacts with the sulfhydryl groups of reduced glutathione. Thioester formation accounts for as much as 50% of the reacted sulfhydryl groups. As much as 60% of the reacted sulfhydryl groups can be accounted for as oxidized glutathione. The stoichiometry of the reaction is approximately 3 moles of sulfhydryl reacting per mole of peroxyacetyl nitrate, and this stoichiometry is ...
متن کاملThe Quantum Yield of N03 from Peroxyacetyl Nitrate Photolysis
Peroxyacetyl nitrate (PAN) vapor was photolyzedat 248 nmandthe N03 photoproduct wasdetected bylaser induced fluorescence. Thequantum yield fortheproduction of N03 was determined by comparison to N 205 photolysis data taken under identical experimental conditions. Contributions to the observed laser induced fluorescence were found to arise from excited state photoproducts such as N02* . The exci...
متن کاملGeneration and detection of the peroxyacetyl radical in the pyrolysis of peroxyacetyl nitrate in a supersonic expansion.
The peroxyacetyl radical (PA, CH3C(O)OO) is generated by flash pyrolysis of peroxyacetyl nitrate (PAN, CH3C(O)OONO2) in a supersonic jet. The 0(0)(0) A2A' <-- X2A'' electronic transition for PA, at ca. 5582 cm(-1), is detected in a supersonically cooled sample by time-of-flight mass spectroscopy in the CH3CO mass channel. Rotational envelope simulation results find that the rotational temperatu...
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ژورنال
عنوان ژورنال: Proceedings of the Symposium on Global Environment
سال: 1999
ISSN: 1884-8419
DOI: 10.2208/proge.7.207